Place pork chops into a resealable plastic bag. In a large glass measuring cup add buttermilk, vanilla extract, chili powder, cumin, salt, sugar, garlic powder and cayenne pepper; stir to combine. Pour brine over chops, seal bag and place in a large bowl; refrigerate overnight. Remove pork chops from bag and discard leftover brine.
Prepare a grill and preheat on medium-high. Grill chops over direct heat until done, about 8-10 minutes per side, turning once.
Add about 1 inch of water and 1/2 teaspoon of lemon extract to a vegetable steamer pot; bring to a boil. Reduce heat, add broccoli florets to steamer basket and steam until done, about 5 minutes. Place broccoli in a serving bowl, drizzle with melted butter; season to taste with salt and pepper.
Place pork chops into a reseable plastic bag. In a large glass measuring cup add buttermilk, vanilla extract, chili powder, cumin, salt, sugar, garlic powder and cayenne pepper; stir to combine. Pour brine over chops, seal bag and place in a large bowl; refrigerate overnight. Remove pork chops from bag and discard leftover brine.
Prepare a grill and preheat on medium-high. Grill chops over direct heat until done, about 8-10 minutes per side, turning once.
Add about 3 cm of water and 1/2 teaspoon of lemon extract to a vegetable steamer pot; bring to a boil. Reduce heat, add broccoli florets to steamer basket and steam until done, about 5 minutes. Place broccoli in a serving bowl, drizzle with melted butter; season to taste with salt and pepper.